In 2004 Corso
et al. from
Osterwalder's group at the
University of Zurich, Switzerland, published
the discovery of a new inorganic nanostructured two dimensional material, called
nanomesh [Science 303, 217 (2004)].
The
boron nitride nanomesh is
composed of single sheet of hexagonal boron nitride (
h-BN) with a honeycomb structure. This sheet
corrugates into a highly regular mesh during a high-temperature exposure of the clean
rhodium to
borazine.
The nanomesh consists of a 3 nm unit cell with "pores" and "wires". The pores are regions
with a close contact between the BN and rhodium while the wires are lifted by about 0.1 nm.
The nanomesh forms in a
self-assembly process, i.e. the organisation of the atoms is driven by the Nature itself
without any human intervention. The super-structure forms due to close but different periodicities
(
lattice constants) of
the
h-BN nanomesh and the
Rh substrate and a
site-dependent BN-Rh bond energy.
The
boron nitride nanomesh
is stable in air, vacuum and liquids. In vacuum it does not decompose up to temperatures of at least
796
oC (1070 K). The
BN nanomesh can serve as a template to assemble molecules and clusters. These
characteristics promise interesting applications in areas like
nanocatalysis,
surface functionalisation,
spintronics and
quantum computing.